Thursday 12 September 2024

WORKSHEET ON Crystal Field Theory (CFT)

 FOR ANSWERS CLICK HERE: ANSWERS

Here’s a tabulation-based question paper (Fill-in-the-Blanks) focused on :-

Crystal Field Theory (CFT) for Class 12, based on NCERT:

TopicFill in the Blanks
1. Crystal Field Theory

According to Crystal Field Theory, the interaction between the __________ and the __________ leads to splitting of d-orbitals in metal ions.


2. d-Orbital Splitting in Octahedral Field


In an octahedral crystal field, the d-orbitals split into two sets: __________ and __________.



3. d-Orbital Splitting in Tetrahedral Field



In a tetrahedral crystal field, the d-orbitals split into two sets: __________ and __________.



4. Energy Difference in Octahedral Field



The energy difference between the two sets of d-orbitals in an octahedral field is called __________ and is represented by __________.



5. Strong Field Ligands




Ligands that cause greater splitting of d-orbitals are called __________ field ligands and result in __________ spin complexes.




6. Weak Field Ligands




Ligands that cause lesser splitting of d-orbitals are called __________ field ligands and usually lead to __________ spin complexes.




7. Splitting in Tetrahedral Complex




In tetrahedral complexes, the d-orbitals split in a reverse manner compared to octahedral complexes, with the __________ set having higher energy.




8. High Spin Complex




A high spin complex occurs when the crystal field splitting energy (Δ) is __________ compared to the pairing energy, leading to __________ electrons.





9. Low Spin Complex





A low spin complex occurs when the crystal field splitting energy (Δ) is __________ compared to the pairing energy, causing maximum __________ of electrons.





10. Factors Affecting Splitting Energy





The magnitude of crystal field splitting (Δ) depends on the nature of the __________ and the __________ of the metal ion.




11. Color of Coordination Compounds




The color of coordination compounds is due to the __________ transitions between the __________ orbitals of the metal ion.





12. Crystal Field Stabilization Energy (CFSE)




The stability of a complex due to crystal field splitting is quantified by the __________, represented as __________.





13. Octahedral Complex Example





An example of an octahedral complex where d-orbitals split according to CFT is __________.




14. Tetrahedral Complex Example




An example of a tetrahedral complex with reverse d-orbital splitting is __________.





15. Magnetic Properties of Complexes





   Complexes with unpaired electrons are __________, while those with        paired electrons are __________.




This question paper format will help students test their understanding of Crystal Field Theory (CFT) and its key concepts.



No comments:

Post a Comment