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Here’s a tabulation-based question paper (Fill-in-the-Blanks) focused on :-
Crystal Field Theory (CFT) for Class 12, based on NCERT:
Topic | Fill in the Blanks |
---|---|
1. Crystal Field Theory | According to Crystal Field Theory, the interaction between the __________ and the __________ leads to splitting of d-orbitals in metal ions. |
2. d-Orbital Splitting in Octahedral Field | In an octahedral crystal field, the d-orbitals split into two sets: __________ and __________. |
3. d-Orbital Splitting in Tetrahedral Field | In a tetrahedral crystal field, the d-orbitals split into two sets: __________ and __________. |
4. Energy Difference in Octahedral Field | The energy difference between the two sets of d-orbitals in an octahedral field is called __________ and is represented by __________. |
5. Strong Field Ligands | Ligands that cause greater splitting of d-orbitals are called __________ field ligands and result in __________ spin complexes. |
6. Weak Field Ligands | Ligands that cause lesser splitting of d-orbitals are called __________ field ligands and usually lead to __________ spin complexes. |
7. Splitting in Tetrahedral Complex | In tetrahedral complexes, the d-orbitals split in a reverse manner compared to octahedral complexes, with the __________ set having higher energy. |
8. High Spin Complex | A high spin complex occurs when the crystal field splitting energy (Δ) is __________ compared to the pairing energy, leading to __________ electrons. |
9. Low Spin Complex | A low spin complex occurs when the crystal field splitting energy (Δ) is __________ compared to the pairing energy, causing maximum __________ of electrons. |
10. Factors Affecting Splitting Energy | The magnitude of crystal field splitting (Δ) depends on the nature of the __________ and the __________ of the metal ion. |
11. Color of Coordination Compounds | The color of coordination compounds is due to the __________ transitions between the __________ orbitals of the metal ion. |
12. Crystal Field Stabilization Energy (CFSE) | The stability of a complex due to crystal field splitting is quantified by the __________, represented as __________. |
13. Octahedral Complex Example | An example of an octahedral complex where d-orbitals split according to CFT is __________. |
14. Tetrahedral Complex Example | An example of a tetrahedral complex with reverse d-orbital splitting is __________. |
15. Magnetic Properties of Complexes | Complexes with unpaired electrons are __________, while those with paired electrons are __________. |
This question paper format will help students test their understanding of Crystal Field Theory (CFT) and its key concepts.
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