Thursday 12 September 2024

PRACTICE WORKSHEET: VBT: COORDINATION COMPOUNDS

 

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Worksheet based on Valence Bond Theory (VBT) from the Coordination Compounds chapter for Class 12 (Fill-in-the-Blanks type):

TopicFill in the Blanks
1. Central Metal Ion
According to VBT, the central __________ ion in a coordination compound undergoes hybridization to form __________ orbitals.



2. Hybridization




The hybridization of central metal in [Co(NH₃)₆]³⁺ is __________, leading to an __________ geometry.




3. Inner Orbital Complex






Complexes where the central metal ion uses its __________ d-orbitals for hybridization are called __________ orbital complexes.



4. Outer Orbital Complex




Complexes where the central metal ion uses its __________ d-orbitals for hybridization are called __________ orbital complexes.





5. Diamagnetism






Complexes in which all electrons are paired exhibit __________ behavior.



6. Paramagnetism






Complexes with unpaired electrons exhibit __________ behavior.




7. Low Spin Complex






Low spin complexes are formed in the presence of __________ field ligands, which cause __________ pairing of electrons.




8. High Spin Complex





High spin complexes are formed in the presence of __________ field ligands, resulting in __________ pairing of electrons.




9. Example of sp³ Hybridization




An example of a complex with sp³ hybridization is __________, which has a __________ geometry.




10. Example of d²sp³ Hybridization




The complex __________ exhibits d²sp³ hybridization and has an __________ geometry.





11. Magnetic Properties






The magnetic properties of a coordination compound depend on the number of __________ electrons in the d-orbitals of the central metal ion.





12. Geometry of [Ni(CN)₄]²⁻







The geometry of the [Ni(CN)₄]²⁻ complex is __________, which is explained by __________ hybridization.




13. Hybrid Orbitals in Octahedral Complexes




In an octahedral complex, the central metal ion undergoes __________ hybridization, involving one s, three p, and two __________ orbitals.





14. Valence Bond Theory Assumption





VBT assumes that the bonding in coordination compounds is due to the overlap of __________ orbitals of the central metal ion with those of the ligands.




15. Limitations of VBT




VBT fails to explain the __________ of coordination compounds and does not provide a detailed explanation of their __________ behavior.




This tabulation will help students focus on key concepts related to Valence Bond Theory (VBT) for coordination compounds.

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