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Worksheet based on Valence Bond Theory (VBT) from the Coordination Compounds chapter for Class 12 (Fill-in-the-Blanks type):
Topic | Fill in the Blanks |
---|---|
1. Central Metal Ion | According to VBT, the central __________ ion in a coordination compound undergoes hybridization to form __________ orbitals. |
2. Hybridization | The hybridization of central metal in [Co(NH₃)₆]³⁺ is __________, leading to an __________ geometry. |
3. Inner Orbital Complex | Complexes where the central metal ion uses its __________ d-orbitals for hybridization are called __________ orbital complexes. |
4. Outer Orbital Complex | Complexes where the central metal ion uses its __________ d-orbitals for hybridization are called __________ orbital complexes. |
5. Diamagnetism | Complexes in which all electrons are paired exhibit __________ behavior. |
6. Paramagnetism | Complexes with unpaired electrons exhibit __________ behavior. |
7. Low Spin Complex | Low spin complexes are formed in the presence of __________ field ligands, which cause __________ pairing of electrons. |
8. High Spin Complex | High spin complexes are formed in the presence of __________ field ligands, resulting in __________ pairing of electrons. |
9. Example of sp³ Hybridization | An example of a complex with sp³ hybridization is __________, which has a __________ geometry. |
10. Example of d²sp³ Hybridization | The complex __________ exhibits d²sp³ hybridization and has an __________ geometry. |
11. Magnetic Properties | The magnetic properties of a coordination compound depend on the number of __________ electrons in the d-orbitals of the central metal ion. |
12. Geometry of [Ni(CN)₄]²⁻ | The geometry of the [Ni(CN)₄]²⁻ complex is __________, which is explained by __________ hybridization. |
13. Hybrid Orbitals in Octahedral Complexes | In an octahedral complex, the central metal ion undergoes __________ hybridization, involving one s, three p, and two __________ orbitals. |
14. Valence Bond Theory Assumption | VBT assumes that the bonding in coordination compounds is due to the overlap of __________ orbitals of the central metal ion with those of the ligands. |
15. Limitations of VBT | VBT fails to explain the __________ of coordination compounds and does not provide a detailed explanation of their __________ behavior. |
This tabulation will help students focus on key concepts related to Valence Bond Theory (VBT) for coordination compounds.
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